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Membrane separation process analysis and design strategies based on thermodynamic efficiency of permeation

Identifieur interne : 001C62 ( Main/Exploration ); précédent : 001C61; suivant : 001C63

Membrane separation process analysis and design strategies based on thermodynamic efficiency of permeation

Auteurs : Jianguo Xu [États-Unis] ; Rakesh Agrawal [États-Unis]

Source :

RBID : ISTEX:1E7624ED86BC5BE10FFBE4B867867930A0DD1894

English descriptors

Abstract

Abstract: In this paper, local thermodynamic efficiency of permeation of a membrane element is introduced and used as a tool to provide insights into the effects of various operating parameters on the performance of a membrane gas separation process. The local thermodynamic efficiency of permeation is a function of membrane selectivity and the pressure ratio across the membrane and is independent of the absolute values of permeabilities and the pressures on either side of the membrane. The local thermodynamic efficiency of permeation analysis provides an indication of the efficiency of separation at each location within a membrane separator. It not only identifies low-efficiency zones but for binary mixtures it also provides an estimate of the potential for efficiency improvement if the local pressure ratios across the membrane could be altered. It also gives an insight into the impact of a sweep stream on the efficiency of a membrane separator and provides guidance on how the pressure ratios should be adjusted to maintain overall high efficiency. This analysis sheds some light on the performance of continuous membrane columns; and it also shows why polymeric film membranes are less than adequate for the production of extremely high-purity products. It is expected to be a very useful tool for optimal design of membrane separation processes.

Url:
DOI: 10.1016/0009-2509(95)00262-6


Affiliations:


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Le document en format XML

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<term>Carbon monoxide</term>
<term>Cascade</term>
<term>Continuous membrane column</term>
<term>Corresponding values</term>
<term>Design strategies</term>
<term>Efficiency function</term>
<term>Efficiency improvement</term>
<term>Energy consumption</term>
<term>Example problem</term>
<term>Exergy loss</term>
<term>Feed pressure</term>
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<term>Membrane separation process</term>
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<term>Membrane separators</term>
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<term>Minimum work</term>
<term>Mole</term>
<term>Mole fraction</term>
<term>Multistage compressor</term>
<term>Negative values</term>
<term>Nonpermeate</term>
<term>Nonpermeate stream</term>
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<term>Optimum pressure ratio</term>
<term>Optimum pressure ratios</term>
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<term>Other side</term>
<term>Overall efficiency</term>
<term>Overall performance</term>
<term>Permeability</term>
<term>Permeation</term>
<term>Permeation approaches</term>
<term>Permeation process</term>
<term>Power consumption</term>
<term>Pressure ratio</term>
<term>Pressure ratios</term>
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<term>Product streams</term>
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<div type="abstract" xml:lang="en">Abstract: In this paper, local thermodynamic efficiency of permeation of a membrane element is introduced and used as a tool to provide insights into the effects of various operating parameters on the performance of a membrane gas separation process. The local thermodynamic efficiency of permeation is a function of membrane selectivity and the pressure ratio across the membrane and is independent of the absolute values of permeabilities and the pressures on either side of the membrane. The local thermodynamic efficiency of permeation analysis provides an indication of the efficiency of separation at each location within a membrane separator. It not only identifies low-efficiency zones but for binary mixtures it also provides an estimate of the potential for efficiency improvement if the local pressure ratios across the membrane could be altered. It also gives an insight into the impact of a sweep stream on the efficiency of a membrane separator and provides guidance on how the pressure ratios should be adjusted to maintain overall high efficiency. This analysis sheds some light on the performance of continuous membrane columns; and it also shows why polymeric film membranes are less than adequate for the production of extremely high-purity products. It is expected to be a very useful tool for optimal design of membrane separation processes.</div>
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